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In gaseous reactions, the equilibrium position is influenced by changes in pressure due to Le Chatelier’s principle. When the pressure is decreased, the system will respond by shifting the equilibrium position in a way that counteracts the change. Specifically, this means that the equilibrium will shift towards the side of the reaction that has more gas molecules.
This occurs because fewer gas molecules will create a higher pressure compared to more gas molecules, which effectively balances out the decrease in pressure. In essence, by shifting to the side with more molecules, the system attempts to increase pressure back toward its original state.
Thus, when pressure is decreased, the shift to the side with more gas molecules represents the system's way of trying to restore a balance. This understanding is crucial for predicting how changes in conditions affect gaseous chemical reactions.